Cyanide - Information on handling, storage and first-aid

Consulting with employees
What is cyanide?
Why is cyanide a dangerous substance?
Legal requirements
Handling
Storage
Disposal
Fires involving cyanide
Further information on poisoning, first aid and medical treatment

1. Consulting with employees

If cyanide is used at your workplace there should be agreed procedures to reduce or eliminate the risk of injury and disease. Employers should consult with employees and safety and health representatives to develop the appropriate procedures and training necessary to protect employees and provide for a safe and healthy workplace as required in the Occupational Safety and Health Act 1984. Copies of the Act can be purchased from WorkSafe or downloaded from this website. Contact WorkSafe via email safety@commerce.wa.gov.au or phone 1300 307 877.

2. What is cyanide?

Cyanides are substances containing the cyanide anion, CN. Cyanides include solid cyanide (such as sodium cyanide and potassium cyanide), cyanides dissolved in liquids, and the gas, hydrogen cyanide (solutions of which may be known as hydrocyanic acid or prussic acid). Hydrogen cyanide gas is commonly called cyanide gas. All forms of cyanide are poisonous.

Uses

Cyanide salts are used in metallurgy, mainly gold extraction, electroplating and metal cleaning. Cyanide gas may be used to fumigate ships.

3. Why is cyanide a dangerous substance?

Cyanide is a fast acting poison in the human body. It affects our ability to use the oxygen we breathe. Severe breathing difficulties develop very rapidly when cyanide is swallowed, inhaled or absorbed through the skin. Highly poisonous cyanide gas can be produced when cyanide solids or liquids are mixed with moisture in air, or with steam, acid, acid fumes or if air is bubbled through a cyanide solution. Cyanide gas has an odour of bitter almonds. 20 to 40 per cent of people are unable to detect its odour and therefore have no warning of its presence. Those who can detect the odour of cyanide gas can detect it at a concentration of around 0.6ppm.

Cyanide gas is highly flammable and reacts violently in some situations (e.g., a large amount of cyanide gas mixed with air may suddenly explode). There is an extremely high risk of explosion if cyanides are exposed to heat or flames. Safety procedures are aimed at preventing the substance from entering the human body and avoiding situations where cyanide solids or liquids might react to produce the highly poisonous and flammable cyanide gas.

4. Legal requirements

The use, handling and storage of cyanide in Western Australia is governed by the Poisons Act 1964 administered by the Department of Health . Cyanide is a substance specified in the Seventh Schedule to the Act. A licence or permit is required for the purchase, sale and use of cyanide from the Department of Health, telephone (08) 9388 4991.

Information on cyanide disposal can be obtained from the Department of Environment and Conservation, telephone (08) 364 6500.

Bulk storage and transport is regulated by the Resources Safety Division of the Department of Mines and Petroleum under the Dangerous Goods legislation.

The Occupational Safety and Health Act 1984 and the Occupational Safety and Health Regulations 1996 apply to the handling of cyanide at WA workplaces (other than minesites).

Cyanide is mostly used in the mining industry. Queries in relation to mine sites should be directed to Resources Safety, Department of Mines and Petroleum, telephone (08) 9358 8002. Other workplaces may contact WorkSafe via email safety@commerce.wa.gov.au or phone 1300 307 877.

5. Handling

Employers must:

provide material safety data sheets (MSDS) to employees and others who may be exposed to cyanide at the workplace.
ensure containers containing cyanide are labelled
ensure that the contents of any pipework or process vessels containing cyanide are adequately identified
assess the risk of injury or harm to people resulting from the use of cyanide
prevent exposure by means other than personal protective clothing or equipment as far as practicable
where it is not practicable to adequately reduce the risk without personal protective clothing or equipment, provide such clothing and equipment and ensure there are systems in place for its safe use and maintenance
provide sufficient information, training and supervision to employees to allow them to use cyanide safely
plan and train for emergencies such as fire, spills and poisoning.

Very small quantities of cyanide, even as little as the size of an aspirin tablet when ingested or inhaled could be lethal. It does not matter whether you are part of a large operation using tonnes of cyanide or just using a few grams in a small workshop. If you work in a place where cyanide is used or stored:

prevent accidents by following the proper procedures for safe handling, storage and disposal;
be able to recognise the early signs and symptoms of cyanide poisoning; and
be prepared for an emergency by learning the correct first-aid treatment.

Avoid poisoning by preventing cyanide from entering the body. Entry to the body can be from:

breathing cyanide gas or dust;
swallowing cyanide solids or liquids; or
absorption of cyanide solutions through the skin.

Effects may occur within seconds to minutes following inhalation and could be delayed several hours following skin absorption.

To avoid breathing in cyanide gas or dust:

ensure cyanide is stored in a closed container;
keep workplaces and stores dry and well ventilated;
ensure that acid chemicals cannot accidentally come in contact with cyanide;
do not smoke or keep cigarettes in areas where cyanide is used or stored;
use the appropriate respiratory equipment;
wash and dry your respiratory equipment after each use and seal it in a clean plastic bag; and
do not store the respiratory equipment in areas where cyanide is used or stored.

The respiratory equipment required will vary depending upon the concentration of dust or gas in the air. Respiratory protective equipment should be selected, used and maintained in accordance with AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices, and should comply with AS/NZS 1716 Respiratory Protective Devices.

To avoid the accidental swallowing of cyanide:

always wash before eating, drinking or smoking;
do not eat or store food/drinks or cigarettes where cyanide is used or stored; and
store cyanide in original labelled containers until the time of use.

To prevent cyanide from being absorbed through the skin:

wear gloves when handling cyanide;
wear a protective apron and face shield whenever there is the slightest chance that you will be splashed;
do not rub your nose or eyes or pick your teeth when handling cyanide. If you have an itch - think before you scratch it! Do not bite your nails;
do not mop up perspiration with the sleeve of your overalls or with a cloth which is kept in the areas where cyanide is used or stored;
handle gloves, overalls and other protective equipment carefully and safely - wash immediately after use and store clean items well away from cyanide; and
wash your hands and face whenever you leave the areas where cyanide is used or stored.

6. Storage

Small quantities of cyanide must be stored separately in a locked poisons cupboard.
For large quantities of cyanide dangerous goods storage regulations apply. Contact Resources Safety, Department of Mines and Petroleum, telephone (08) 9358 8002.
The cyanide store must not contain acids.
The store should have no sharp edges or protrusions, which might damage cyanide containers or their labels.
Keep cyanide in securely closed, original containers.
Check cyanide containers regularly for damage or deterioration.
Arrange cyanide stock so that the oldest is used first.
Before taking cyanide from a drum, first remove the lid, then move away to let the accumulated gas out of the container before returning to handle the cyanide.
A notice of action to be taken in case of suspected poisoning should be displayed in a prominent place in the store, work areas and first-aid station.
Make sure that all employees understand the safety procedures associated with storing cyanide. Include these procedures in your safety training programme.

Remember - do not eat, drink or smoke in a cyanide store and make sure that food, drinks, cigarettes, respiratory equipment, clothing and protective equipment are not kept in any of the areas where cyanide is used or stored.

7. Disposal

Thoroughly rinse empty containers with large amounts of water. The rinse should be used in the cyanide process. Puncture or crush empty containers and dispose of them at approved municipal disposal sites. For further information on disposal contact: Department of Environment and Conservation, telephone (08) 6364 6500.

8. Fires involving cyanide

Cyanide salts or solutions are not combustible, but may generate highly toxic, flammable, corrosive and explosive hydrogen cyanide gas if in contact with water, carbon dioxide fire extinguishers, or some foam fire extinguishers if these contain acidic agents. If a fire occurs in the vicinity of cyanide:

Evacuate the area immediately and call the Fire and Emergency Services Authority (FESA).
Use breathing apparatus and full body protective clothing to rescue anyone overcome by poisonous gases or trapped by the fire.
Fire-fighters must wear breathing apparatus and full body protective clothing.
Use dry chemical fire extinguishers or dry sand and water spray or fog to put the fire out. Do not use water streams. Do not use carbon dioxide [CO2].

Remember - cyanides can react with heat or water to produce the highly poisonous and flammable cyanide gas and there is a very high risk of explosion.

9. Further information on poisoning, first aid and medical treatment

Further information on poisoning, first aid and medical treatment is available from the Resources Safety Division of the Department of Mines and Petroleum here.

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